A 1D coordination polymer built on asymmetric μ1,1,3-azide bridge: from unusual topology to magnetic properties and Cu(ii)/Cu(i) redox reversibility
نویسندگان
چکیده
منابع مشابه
3D Mn(II) coordination polymer with alternating azide/azide/formate/formate bridged chains: synthesis, structure and magnetic properties.
A new 3D Mn(II) coordination polymer, [Mn(2)(HCO(2))(L)(2)(N(3)) x MeOH](infinity) (1) (L = nicotinate N-oxide), was synthesized by a solvothermal reaction and characterized magnetically. Complex 1 is a typical antiferromagnet with alternating azide/azide/formate/formate bridges, exhibiting a new -J(1)J(1)J(2)J(2)- coupling sequence. This is the first complex to contain an azide, formate and an...
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The azide anion is a short bridging ligand that has been used extensively to construct magnetic coordination polymers, and fundamental magneto-structural correlations have been substantiated by theoretical calculations. The copper(II) coordination polymer poly[bis(μ-azido-κ(2)N(1):N(1))(μ4-homophthalato-κ(4)O:O':O'':O''')bis(pyridine-κN)dicopper(II)], [Cu2(C9H6O4)(N3)2(C5H5N)2]n, was synthesize...
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By using a neutral inner-salt-type dicarboxylate as coligand, a novel two-dimensional (2D) manganese(II) coordination polymer, [Mn(L)(N(3))]ClO(4) x 1/2 H(2)O (L = 1,3-bis(3-carboxylatopyridinium)propane), was synthesized, and characterized by X-ray crystallography and magnetic measurements. The compound contains uniform Mn(II) chains with simultaneous azide and carboxylate bridges between adja...
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Six homochiral coordination polymers 1-6 based on an enantiopure elongated and bent bipyridine ligand were synthesized and characterized by single-crystal X-ray diffraction studies. The framework structures of all six compounds were built up from similar 1D polymeric chains composed of 46-membered metallomacrocycles. Four distinct packing patterns were observed for this family of coordination p...
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Department of Inorganic Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska Str. 64, Kyiv 01033, Ukraine Chemistry, School of Biomedical, Biomolecular and Chemical Sciences, University of Western Australia, Crawley, Western Australia 6009, Australia c Faculty of Chemistry, University of Wroclaw, 14 Joliot-Curie Str., 50-383 Wroclaw, Poland National High Magnetic Field Laborato...
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ژورنال
عنوان ژورنال: New Journal of Chemistry
سال: 2012
ISSN: 1144-0546,1369-9261
DOI: 10.1039/c2nj40302a